Recycling industrial waste
Although many government programs are concentrated on recycling at home, 64% of waste in the United Kingdom is generated by industry. The focus of many recycling programs done by industry is the cost–effectiveness of recycling. The ubiquitous nature of cardboard packaging makes cardboard a commonly recycled waste product by companies that deal heavily in packaged goods, like retail stores, warehouses, and distributors of goods. Other industries deal in niche or specialized products, depending on the nature of the waste materials that are present.
The glass, lumber, wood pulp and paper manufacturers all deal directly in commonly recycled materials; however, old rubber tires may be collected and recycled by independent tire dealers for a profit.
Levels of metals recycling are generally low. In 2010, the International Resource Panel, hosted by the United Nations Environment Programme (UNEP) published reports on metal stocks that exist within society and their recycling rates. The Panel reported that the increase in the use of metals during the 20th and into the 21st century has led to a substantial shift in metal stocks from below ground to use in applications within society above ground. For example, the in-use stock of copper in the USA grew from 73 to 238 kg per capita between 1932 and 1999.
The report authors observed that, as metals are inherently recyclable, the metal stocks in society can serve as huge mines above ground (the term "urban mining" has been coined with this idea in mind). However, they found that the recycling rates of many metals are low. The report warned that the recycling rates of some rare metals used in applications such as mobile phones, battery packs for hybrid cars and fuel cells, are so low that unless future end-of-life recycling rates are dramatically stepped up these critical metals will become unavailable for use in modern technology.
The military recycles some metals. The U.S. Navy's Ship Disposal Program uses ship breaking to reclaim the steel of old vessels. Ships may also be sunk to create an artificial reef. Uranium is a dense metal that has qualities superior to lead and titanium for many military and industrial uses. The uranium left over from processing it into nuclear weapons and fuel for nuclear reactors is called depleted uranium, and is used by all branches of the U.S. military for the development of such things as armour-piercing shells and shielding.
The construction industry may recycle concrete and old road surface pavement, selling their waste materials for profit.
Some industries, like the renewable energy industry and solar photovoltaic technology, in particular, are being proactive in setting up recycling policies even before there is considerable volume to their waste streams, anticipating future demand during their rapid growth.
Recycling of plastics is more difficult, as most programs are not able to reach the necessary level of quality. Recycling of PVC often results in downcycling of the material, which means only products of lower quality standard can be made with the recycled material. A new approach which allows an equal level of quality is the Vinyloop process. It was used after the London Olympics 2012 to fulfill the PVC Policy.
E-waste recyclingedit
E-waste is a growing problem, accounting for 20–50 million metric tons of global waste per year according to the EPA. It is also the fastest growing waste stream in the EU. Many recyclers do not recycle e-waste responsibly. After the cargo barge Khian Sea dumped 14,000 metric tons of toxic ash in Haiti, the Basel Convention was formed to stem the flow of hazardous substances into poorer countries. They created the e-Stewards certification to ensure that recyclers are held to the highest standards for environmental responsibility and to help consumers identify responsible recyclers. This works alongside other prominent legislation, such as the Waste Electrical and Electronic Equipment Directive of the EU the United States National Computer Recycling Act, to prevent poisonous chemicals from entering waterways and the atmosphere.
In the recycling process, television sets, monitors, cell phones, and computers are typically tested for reuse and repaired. If broken, they may be disassembled for parts still having high value if labor is cheap enough. Other e-waste is shredded to pieces roughly 10 centimetres (3.9 in) in size, and manually checked to separate out toxic batteries and capacitors which contain poisonous metals. The remaining pieces are further shredded to 10 millimetres (0.39 in) particles and passed under a magnet to remove ferrous metals. An eddy current ejects non-ferrous metals, which are sorted by density either by a centrifuge or vibrating plates. Precious metals can be dissolved in acid, sorted, and smelted into ingots. The remaining glass and plastic fractions are separated by density and sold to re-processors. Television sets and monitors must be manually disassembled to remove lead from CRTs or the mercury backlight from LCDs.
Plastic recyclingedit
Plastic recycling is the process of recovering scrap or waste plastic and reprocessing the material into useful products, sometimes completely different in form from their original state. For instance, this could mean melting down soft drink bottles and then casting them as plastic chairs and tables. For some types of plastic, the same piece of plastic can only be recycled about 2–3 times before its quality decreases to the point where it can no longer be used.
Physical recyclingedit
Some plastics are remelted to form new plastic objects; for example, PET water bottles can be converted into polyester destined for clothing. A disadvantage of this type of recycling is that the molecular weight of the polymer can change further and the levels of unwanted substances in the plastic can increase with each remelt.citation needed
A commercial-built recycling facility was sent to the International Space Station in late 2019. The facility will take in plastic waste and unneeded plastic parts and physically convert them into spools of feedstock for the space station additive manufacturing facility used for in-space 3D printing.
Chemical recyclingedit
For some polymers, it is possible to convert them back into monomers, for example, PET can be treated with an alcohol and a catalyst to form a dialkyl terephthalate. The terephthalate diester can be used with ethylene glycol to form a new polyester polymer, thus making it possible to use the pure polymer again. In 2019, Eastman Chemical Company announced initiatives of methanolysis and syngas designed to handle a greater variety of used material.
Waste plastic pyrolysis to fuel oiledit
Another process involves the conversion of assorted polymers into petroleum by a much less precise thermal depolymerization process. Such a process would be able to accept almost any polymer or mix of polymers, including thermoset materials such as vulcanized rubber tires and the biopolymers in feathers and other agricultural waste. Like natural petroleum, the chemicals produced can be used as fuels or as feedstock. A RESEM Technology plant of this type in Carthage, Missouri, US, uses turkey waste as input material. Gasification is a similar process but is not technically recycling since polymers are not likely to become the result. Plastic Pyrolysis can convert petroleum based waste streams such as plastics into quality fuels, carbons. Given below is the list of suitable plastic raw materials for pyrolysis:
- Mixed plastic (HDPE, LDPE, PE, PP, Nylon, Teflon, PS, ABS, FRP, etc.)
- Mixed waste plastic from waste paper mill
- Multi-layered plastic
Comments
Post a Comment